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Dehydration of α,α-dimethylcyclopropanemethanol and accompanying transformations of the hydrocarbons formed over acidic catalysts

 

作者: L.Kh.Freidlin,   V.Z.Sharf,   M.A.Abidov,   V.G.Glukhovtsev,  

 

期刊: Bulletin of the Academy of Sciences of the USSR, Division of chemical science  (Springer Available online 2004)
卷期: Volume 12, issue 10  

页码: 1673-1676

 

ISSN:0568-5230

 

年代: 2004

 

DOI:10.1007/BF00845799

 

出版商: Springer_US-Boston

 

数据来源: Springer

 

摘要:

1.The dehyration of α,α-dimethylcyclopropanemethanol over acidic catalysts goes considerably more readily than the opening of the cyclopropane ring of the 2-cyclopropylpropene formed. Over alumina and calcium phosphate almost pure 2-cyclopropylpropene is obtained in yields of 60 and 78% respectively.2.The 2-cyclopropylpropene formed by the dehydration of the alcohol is isomerized into cis-2-methyl-1,3-pentadiene and 2-methyl-1,4-pentadiene. The latter is converted into cis-2-methyl-1,3-pentadiene, which is further isomerized into the trans for

 

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