Dehydration of α,α-dimethylcyclopropanemethanol and accompanying transformations of the hydrocarbons formed over acidic catalysts
作者:
L.Kh.Freidlin,
V.Z.Sharf,
M.A.Abidov,
V.G.Glukhovtsev,
期刊:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science
(Springer Available online 2004)
卷期:
Volume 12,
issue 10
页码: 1673-1676
ISSN:0568-5230
年代: 2004
DOI:10.1007/BF00845799
出版商: Springer_US-Boston
数据来源: Springer
摘要:
1.The dehyration of α,α-dimethylcyclopropanemethanol over acidic catalysts goes considerably more readily than the opening of the cyclopropane ring of the 2-cyclopropylpropene formed. Over alumina and calcium phosphate almost pure 2-cyclopropylpropene is obtained in yields of 60 and 78% respectively.2.The 2-cyclopropylpropene formed by the dehydration of the alcohol is isomerized into cis-2-methyl-1,3-pentadiene and 2-methyl-1,4-pentadiene. The latter is converted into cis-2-methyl-1,3-pentadiene, which is further isomerized into the trans for
点击下载:
PDF
(254KB)
返 回