STUDIES ON REACTIONS RELATING TO CARBOHYDRATES AND POLYSACCHARIDES.: PART XXVI. STRUCTURE OF ACETONE GLYCEROL
作者:
Harold Hibbert,
J. G. Morazain,
期刊:
Canadian Journal of Research
(NRC Available online 1930)
卷期:
Volume 2,
issue 1
页码: 35-41
ISSN:1923-4287
年代: 1930
DOI:10.1139/cjr30-005
出版商: NRC Research Press
数据来源: NRC
摘要:
The condensation of acetone with glycerol has been carried out in a neutral medium, at a low temperature, and the product shown to consist entirely of the five-membered isopropylidene-glycerol ketal. Based on this fact, the use of the substance for the determination of the structure of fats is therefore warranted. Isopropylidene-glycerol and its acetate readily hydrolyse on heating with water.No satisfactory explanation can, as yet, be offered for the non-formation of the six-membered ketal under the conditions outlined.Acetone, as previously shown by other workers, is capable of forming a six-membered cyclic ketal with glycerol-β-methyl ether, dihydroxy acetone, pentaerythritol and certain carbohydrates.
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