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Goldstone mode and domain mode relaxation in ferroelectric phases of 4′-[(S,S) - 2,3 - epoxyhexyloxy] phenyl 4-(decyloxy)benzoate (EHPDB)

 

作者: M. Marzec,   R. Dabrowski,   A. Fąfara,   W. Haase,   S. Hiller,   S. Wróbel,  

 

期刊: Ferroelectrics  (Taylor Available online 1996)
卷期: Volume 180, issue 1  

页码: 127-135

 

ISSN:0015-0193

 

年代: 1996

 

DOI:10.1080/00150199608223647

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Dielectric and electrooptic studies of 4′-[(S,S)-2,3-epoxyhexyloxy] phenyl 4-(decyloxy) benzoate (in short EHPDB) have been done and Goldstone mode (GM) and domain mode (DM) relaxation have been observed. The dielectric measurements have been done in the temperature range between 57˚C and 80˚C covering the N*, SmA*, SmC* and a metastable S3phase. Temperature dependences of the dielectric parameters of GM and DM show that the phase known before as S3phase is one of the ferroelectric phases (SmI* of SmF*). The electrooptic measurements have been performed on uniformly aligned samples using polarizing microscope. Temperature dependencies of the dielectric and electrooptic data of the pitch of helix and the critical field for unwinding the helix show that the SmC*-(SmA*)-N*transition is of the first order type.

 

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