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On the Synthesis of Hydroterphenyl Derivatives by Grignard Reaction

 

作者: Daniel Y. Chang,   Nan Shieh,  

 

期刊: Journal of the Chinese Chemical Society  (WILEY Available online 1954)
卷期: Volume 1, issue 1  

页码: 64-70

 

ISSN:0009-4536

 

年代: 1954

 

DOI:10.1002/jccs.195400007

 

出版商: WILEY‐VCH Verlag

 

数据来源: WILEY

 

摘要:

AbstractThe reaction between p‐bromophenylmagnesium bromide and cyclo‐h‐exanone has been reinvestigated. p‐Bromophenylcyclohexene (tetrahydro‐p‐bromodiphenyl), dehydration product of the tertiary alcohol resulted from the above reaction, was converted into the corresponding organomagnesium compound by a special method. The latter was in turn allowed to react with cyclohexanone, resulting in the formation of hydroterphenyl

 

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