Automatic Computerized Analysis of Multi-Exponential Decay Curves
作者:
MargaretY. Brooks,
JamesF. Rusling,
期刊:
Analytical Letters
(Taylor Available online 1985)
卷期:
Volume 18,
issue 16
页码: 2021-2032
ISSN:0003-2719
年代: 1985
DOI:10.1080/00032718508067968
出版商: Taylor & Francis Group
关键词: exponential decay;nonlinear regression;deviation-pattern recognition;luminescence lifetimes;computer modeling
数据来源: Taylor
摘要:
A prototype method is described which automatically analyzes exponential decay curves by using nonlinear regression analysis and deviation pattern recognition. Lifetimes and preexponential factors are computed for the proper model. The program successfully classified simulated data consisting of one, two, or three exponentials when noise followed a Poisson distribution. However, for real luminescence decay data, systematic instrumental noise of higher frequency tended to obscure low frequency deviations from incorrect models in smoothed deviation plots. This factor complicated classification of multi-exponential data, although the program easily distinguished between single and multiple exponential behavior.
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