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Automatic Computerized Analysis of Multi-Exponential Decay Curves

 

作者: MargaretY. Brooks,   JamesF. Rusling,  

 

期刊: Analytical Letters  (Taylor Available online 1985)
卷期: Volume 18, issue 16  

页码: 2021-2032

 

ISSN:0003-2719

 

年代: 1985

 

DOI:10.1080/00032718508067968

 

出版商: Taylor & Francis Group

 

关键词: exponential decay;nonlinear regression;deviation-pattern recognition;luminescence lifetimes;computer modeling

 

数据来源: Taylor

 

摘要:

A prototype method is described which automatically analyzes exponential decay curves by using nonlinear regression analysis and deviation pattern recognition. Lifetimes and preexponential factors are computed for the proper model. The program successfully classified simulated data consisting of one, two, or three exponentials when noise followed a Poisson distribution. However, for real luminescence decay data, systematic instrumental noise of higher frequency tended to obscure low frequency deviations from incorrect models in smoothed deviation plots. This factor complicated classification of multi-exponential data, although the program easily distinguished between single and multiple exponential behavior.

 

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