Conduction in non-crystalline systems
作者:
N.F. Mott,
E.A. Davis,
期刊:
Philosophical Magazine
(Taylor Available online 1968)
卷期:
Volume 17,
issue 150
页码: 1269-1284
ISSN:0031-8086
年代: 1968
DOI:10.1080/14786436808223201
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The metal-insulator transition for donors in a semiconductor is examined in the light of the work of Kohn on the nature of the transition. Kohn's work predicts, for a rigid crystalline lattice, an infinite series of second-order transitions as the interatomic distance approaches the transition point. The original work of Mott on the transition suggested that it should be of the first order with a discontinuous change in the number of free electrons at T=0, unless the dielectric constant k could be shown to tend to infinity at the transition point. In this paper it is suggested that Kohn's theory may allow this to occur. The evidence from the behaviour of doped semiconductors is analysed; in this case the effect of the random (non-crystalline) distribution of the centres must be allowed for. It is suggested that Kohn's charge density waves must be replaced by random fluctuations of charge density, occurring near the transition point and due, as is the transition, to electron-electron interaction. The possibility that k should tend to infinity exists here as in Kohn's model. It appears therefore that the random distribution of the centres does not change the nature of the transition in any essential way, and that it is second order in either case.
点击下载:
PDF (833KB)
返 回