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Optical Properties of Ho(NO3)36H2O: Organic Acid Complexes

 

作者: S. Buddhudu,   V.N. Rangarajan,   G. Amaranath,   R. Harinath,   A.Suresh Kumar,  

 

期刊: Physics and Chemistry of Liquids  (Taylor Available online 1991)
卷期: Volume 23, issue 2  

页码: 61-68

 

ISSN:0031-9104

 

年代: 1991

 

DOI:10.1080/00319109108030635

 

出版商: Taylor & Francis Group

 

关键词: Spectral intensities;complexes bonding nature

 

数据来源: Taylor

 

摘要:

Optical absorption studies have been carried out from the UV to NIR for Ho3+ions (0.1 M%) mixed organic acids namely anthrolinic, benzoic, salicylic and pthalic acids. Spectral intensities of various observed bands of Ho3+have neen affected very significantly depending upon the surrounding environment. We made a correlation between the intensity parameters and the spectral intensities quite clearly by the application of Judd-Ofelt theory. Of the various levels recorded, particularly the energy level5G6←5I8has shown a distinctive phenomenon in its intensity magnitudes as a function of the host. We have also examined the bonding nature of the complexes, as ionic for Ho3+in four different fluorescing organic acids.

 

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