Thin‐layer adsorption chromatography with mixed mobile phases. 4. Extension of Ościk's equation to heterogeneous adsorbents
作者:
J. K. Różyło,
J. Ościk,
B. Ościk‐Mendyk,
M. Jaroniec,
期刊:
Journal of High Resolution Chromatography
(WILEY Available online 1981)
卷期:
Volume 4,
issue 1
页码: 17-23
ISSN:0935-6304
年代: 1981
DOI:10.1002/jhrc.1240040105
出版商: Wiley Subscription Services, Inc., A Wiley Company
关键词: Thin‐layer chromatography, TLC;Liquid chromatography, LC;Adsorption chromatography;LC with mixed mobile phases;Heterogeneity effects in adsorption chromatography
数据来源: WILEY
摘要:
AbstractIn this paper the equation for thin‐layer adsorption chromatography with multicomponent mobile phases, proposed by Ościk in 1965 is extended to energetically heterogeneous solid surfaces. Other forms of this equation, more convenient in practical applications, are presented. Model calculations are made for TLC with binary mobile phases according to the modified form of Ościk's equation. Finally, this equation is compared with that of Sny
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