Hydrodynamic Behavior of Semirigid Polymer at a Solid‐Liquid Interface
作者:
A. Omari,
M. Moan,
G. Chauveteau,
期刊:
Journal of Rheology
(AIP Available online 1989)
卷期:
Volume 33,
issue 1
页码: 1-13
ISSN:0148-6055
年代: 1989
DOI:10.1122/1.550056
出版商: The Society of Rheology
数据来源: AIP
摘要:
The apparent viscosity of dilute and semidilute xanthan solutions flowing through small cylindrical pores, under conditions where there is no adsorption effect, were accurately determined in Newtonian and shear‐thinning regimes. The analysis of the results using a two‐fluid flow model shows that the hydrodynamic thickness of the depletion layer near the pore wall is closely related to the equivalent rod length of the macromolecule, but seems to be insensitive to the persistence length. The hydrodynamic thickness does not depend on polymer concentration as expected for a semirigid polymer and decreases slightly as shear rate increases.
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