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The interaction polarizability of two nitrogen molecules

 

作者: DavidG. Bounds,   Alan Hinchliffe,   ColinJ. Spicer,  

 

期刊: Molecular Physics  (Taylor Available online 1981)
卷期: Volume 42, issue 1  

页码: 73-82

 

ISSN:0026-8976

 

年代: 1981

 

DOI:10.1080/00268978100100061

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The incremental polarizability which occurs when two nitrogen molecules interact has been calculated by theab initiofinite field SCF method. For the configurations studied the [5s, 4p, 1d] gaussian basis set gives a potential surface which is in qualitative agreement with otherab initioestimates. At separations around the energy minimum the interaction α is well represented by the dipole-induced dipole model. At closer separations the deviations from DID behaviour are qualitively similar to those which occur in rare gas diatoms.

 

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