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Nitrogen-doping effects on electrical, optical, and structural properties in hydrogenated amorphous silicon

 

作者: Atsushi Masuda,   Ken-ichi Itoh,   Kazuko Matsuda,   Yasuto Yonezawa,   Minoru Kumeda,   Tatsuo Shimizu,  

 

期刊: Journal of Applied Physics  (AIP Available online 1997)
卷期: Volume 81, issue 10  

页码: 6729-6737

 

ISSN:0021-8979

 

年代: 1997

 

DOI:10.1063/1.365215

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Electrical, optical, and structural properties of nitrogen-doped hydrogenated amorphous silicon films with the N content up to about 12 at. &percent; are systematically studied using electrical conductivity measurements, electron-spin resonance, light-induced electron-spin resonance, constant photocurrent method, optical absorption spectrophotometry, IR absorption spectroscopy, Raman scattering spectroscopy, and x-ray photoelectron spectroscopy. Both behaviors of the dark conductivity and the charged-dangling-bond density against the N content suggest that most of charged dangling bonds originate from potential fluctuations. Only part of charged dangling bonds created by the N doping up to 2 at. &percent; originate from positively charged fourfold-coordinated N. The decay behavior of the photoconductivity after turning off the probing light also supports that most of charged dangling bonds in N-doped hydrogenated amorphous silicon do not originate from positively charged fourfold-coordinated N. A possible origin of potential fluctuations is increased fluctuations in the net electron density at Si sites accompanying structural randomness caused by the N doping. ©1997 American Institute of Physics.

 

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