Infra-red spectrum of CH3F at very high resolution : Accidental and essential resonances in ν2+ ν3and ν3+ ν5bands
作者:
Michel Betrencourt,
Mireille Morillon-Chapey,
期刊:
Molecular Physics
(Taylor Available online 1977)
卷期:
Volume 33,
issue 1
页码: 83-94
ISSN:0026-8976
年代: 1977
DOI:10.1080/00268977700103071
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The analysis of the Fourier transform spectrum, with a resolution of 0·008 cm-1, of the combination bands ν2+ ν3(A1species) and ν3+ ν5(Especies) of CH3F has allowed the study ofx-yCoriolis resonance between the states υ2= 1 and υ5= 1. The vibrational levels υ2= υ3= 1 and υ3= υ5= 1 are 15 cm-1apart and the interaction is very strong. The combination of the Coriolis resonance and the essential interaction ofl-type (2, 2) in ν3+ ν5gives rise to a ‘giant’l-type doubling : forJ=25 the shift between the levels is about 17 cm-1.
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