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Infra-red spectrum of CH3F at very high resolution : Accidental and essential resonances in ν2+ ν3and ν3+ ν5bands

 

作者: Michel Betrencourt,   Mireille Morillon-Chapey,  

 

期刊: Molecular Physics  (Taylor Available online 1977)
卷期: Volume 33, issue 1  

页码: 83-94

 

ISSN:0026-8976

 

年代: 1977

 

DOI:10.1080/00268977700103071

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The analysis of the Fourier transform spectrum, with a resolution of 0·008 cm-1, of the combination bands ν2+ ν3(A1species) and ν3+ ν5(Especies) of CH3F has allowed the study ofx-yCoriolis resonance between the states υ2= 1 and υ5= 1. The vibrational levels υ2= υ3= 1 and υ3= υ5= 1 are 15 cm-1apart and the interaction is very strong. The combination of the Coriolis resonance and the essential interaction ofl-type (2, 2) in ν3+ ν5gives rise to a ‘giant’l-type doubling : forJ=25 the shift between the levels is about 17 cm-1.

 

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