首页   按分类浏览 期刊浏览 卷期浏览 Chiroptical properties of steroid 1,3-diaxial diols in the presence of [Mo2(OAc)4]
Chiroptical properties of steroid 1,3-diaxial diols in the presence of [Mo2(OAc)4]

 

作者: JadwigaFrelek,   GüntherSnatzke,   WojciechJ.Szczepek,  

 

期刊: Fresenius' Journal of Analytical Chemistry  （Springer Available online 2004）
卷期: Volume 345, issue 11  

页码: 683-687

 

ISSN:0937-0633

 

年代: 2004

 

DOI:10.1007/BF00325835

 

出版商: Springer-Verlag-Berlin-Heidelberg

 

数据来源: Springer

 

摘要:

Bidentate complexes of dimolybdenum tetraacetate with 1,3-diaxial diols show Cotton effects around 490–540 nm (CD band I), 400–440 nm (II), 350–380 nm (III), 320 nm (IV) and 280 nm (V). The sign of the Cotton effect II can be predicted by a proposed sector rule. It seems that from the Cotton effects for cyclic 1,3-diols the absolute configurations or conformations can be obt

 

点击下载:  PDF (419KB)



返 回