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A defect model for the optical and EPR activity of the T-center in yttrium-stabilized zirconia

 

作者: C.B. Azzoni,   L. Bolis,   P. Camagni,   G.C. Campagnoli,   M.De Simone,  

 

期刊: Radiation Effects and Defects in Solids  (Taylor Available online 1995)
卷期: Volume 134, issue 1-4  

页码: 485-488

 

ISSN:1042-0150

 

年代: 1995

 

DOI:10.1080/10420159508227274

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Direct quantitative correlations have been recently observed between the T-centre EPR signal and an optical absorption band at 370 nm, in X-irradiated YSZ, suggesting that the colour centre and the paramagnetic centre might be the same entity. In order to confirm this hypothesis, theoretical modeling was undertaken, where by appropriate refinement the known electronic structure of the T-centre is shown to be compatible with an optical transition, having an oscillator strength of the correct magnitude.

 

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