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On the Ionic Equilibrium between Complexes in Molten Fluoroaluminates

 

作者: Z. Akdeniz,   K. Tankeshwar,   M.P. Tosi,  

 

期刊: Physics and Chemistry of Liquids  （Taylor Available online 1991）
卷期: Volume 23, issue 4  

页码: 259-263

 

ISSN:0031-9104

 

年代: 1991

 

DOI:10.1080/00319109108027262

 

出版商: Taylor & Francis Group

 

关键词: Raman scattering;molten cryolite

 

数据来源: Taylor

 

摘要:

We discuss theoretically (i) the effect of the alkali cation species on the ionic equilibrium between (AlF6)3-and (AlF4)−complexes in molten alkali fluoroaluminates, and (ii) the possible presence of (AlF5)2-complexes in molten cryolite, in relation to very recent Raman scattering experiments by Gilbert and Materne.

 

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