Significance of Network Chain-Length Distribution in Chemical Stress Relaxation Studies
作者:
A.L. Andrady,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1980)
卷期:
Volume 14,
issue 8
页码: 1197-1207
ISSN:0022-233X
年代: 1980
DOI:10.1080/00222338008056739
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The theoretically expected network chain-length distribution for networks where the cross-link points are randomly distributed in the bulk of the material would contain a significant fraction of network chains which are much shorter than the average chain length. The contribution of these very short chains to the stress born by a network is an important consideration in chemical stress relaxation studies. It is proposed that by use of a gamma distribution function as a “functional” network chain-length distribution, the effect of such short network chains might be taken into account in deriving stress-time expressions for chemical stress relaxation studies. While this procedure yields a simple expression for the fractional residual stress at a given extent of scission, the error involved in neglecting the effect of the chain-length distribution appears to be small.
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