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Investigation of the local structure of the tetragonal Ni2+-vlicenter in LiCl:Ni2+crystal from EPR parameters

 

作者: Zheng Wen-Chen,  

 

期刊: Radiation Effects and Defects in Solids  (Taylor Available online 1996)
卷期: Volume 139, issue 3  

页码: 215-219

 

ISSN:1042-0150

 

年代: 1996

 

DOI:10.1080/10420159608211549

 

出版商: Taylor & Francis Group

 

关键词: electron paramagnetic resonance;local structure;crystal-field theory;Ni2+;LiCl

 

数据来源: Taylor

 

摘要:

The zero-field splitting D and the g factor g‖, Δg (= g‖- g1) of the tetragonal Ni2+-VLicenter in LiCl:Ni2+crystal have been studied from the high-order perturbation formulas of these EPR parameters for d8ions in tetragonal symmetry. On the basis of this, the local structure of this tetragonal center is determined and the negative sign of the zero-field splitting D of the crystal is obtained.

 

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