Investigation of the local structure of the tetragonal Ni2+-vlicenter in LiCl:Ni2+crystal from EPR parameters
作者:
Zheng Wen-Chen,
期刊:
Radiation Effects and Defects in Solids
(Taylor Available online 1996)
卷期:
Volume 139,
issue 3
页码: 215-219
ISSN:1042-0150
年代: 1996
DOI:10.1080/10420159608211549
出版商: Taylor & Francis Group
关键词: electron paramagnetic resonance;local structure;crystal-field theory;Ni2+;LiCl
数据来源: Taylor
摘要:
The zero-field splitting D and the g factor g‖, Δg (= g‖- g1) of the tetragonal Ni2+-VLicenter in LiCl:Ni2+crystal have been studied from the high-order perturbation formulas of these EPR parameters for d8ions in tetragonal symmetry. On the basis of this, the local structure of this tetragonal center is determined and the negative sign of the zero-field splitting D of the crystal is obtained.
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