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Surface tensiometer utilizing laser‐beam reflection at cylindrical liquid menisci

 

作者: Kenji Ishida,   Shinji Kinoshita,   Yasuhiko H. Mori,  

 

期刊: Review of Scientific Instruments  (AIP Available online 1993)
卷期: Volume 64, issue 5  

页码: 1324-1329

 

ISSN:0034-6748

 

年代: 1993

 

DOI:10.1063/1.1144087

 

出版商: AIP

 

数据来源: AIP

 

摘要:

A surface tensiometer has been devised which is based on the mathematical solution, as a function of the surface tension of a liquid, of the profile of a cylindrical meniscus formed against a flat plate brought into contact with the free surface of a quiescent pool of the liquid. Only the angles of inclination of the meniscus at two arbitrary points are to be actually measured; the angle at each point is known accurately by observing the angle of reflection of a laser beam vertically irradiated onto the point. No knowledge of the contact angle on the plate is required. The tensiometer is suitable for the study of surface adsorption or of insoluble monolayers just the same as in the Wilhelmy plate method, but it is still superior to the Wilhelmy plate tensiometers and other conventional surface balances in its applicability to the measurements in an atmosphere completely insulated from the laboratory air. An apparatus is demonstrated that has been constructed primarily for the measurements of surface tensions of aqueous lithium bromide (LiBr) solutions with higher alcohol additives, i.e., working fluids of absorption heat pumps, under reduced pressures and elevated temperatures.

 

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