首页   按字顺浏览 期刊浏览 卷期浏览 Effects of Cation Symmetry and its Packing on the Mixed-Valence State of Binuclear Ferr...
Effects of Cation Symmetry and its Packing on the Mixed-Valence State of Binuclear Ferrocenes

 

作者: Satoru Nakashima,   Takashi Oda,   Tsutomu Okuda,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  （Taylor Available online 2000）
卷期: Volume 342, issue 1  

页码: 267-272

 

ISSN:1058-725X

 

年代: 2000

 

DOI:10.1080/10587250008038276

 

出版商: Taylor & Francis Group

 

关键词: mixed-valence state;binuclear ferrocene;asymmetric carbon;57Fe Mössbauer spectroscopy;cation symmetry;packing effect

 

数据来源: Taylor

 

摘要:

The mixed-valence state for (S,S), (R,R), and DL samples in 1′,1‴bis(2-phenylbutyl)-1,1″-biferrocenium salt was investigated and compared with that in 1′,1‴-bis(2-methylbutyl)- 1,1″-biferrocenium triiodide. The difference between them was attributed to the effect of benzene ring. It was understood that the packing effect becomes more substantial by introducing the benzene ring in the substituent.

 

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