CHEMISORPTION AND EXCHANGE WITH DEUTERIUM OF METHANE ON METALS
作者:
A. Frennet,
期刊:
Catalysis Reviews
(Taylor Available online 1974)
卷期:
Volume 10,
issue 1
页码: 37-68
ISSN:0161-4940
年代: 1974
DOI:10.1080/01614947408079626
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The interaction of methane with metal catalysts has received less attention than that of hydrocarbons containing two or more carbon atoms [1]. Yet methane is interesting because its electronic structure resembles that of a rare gas and it possesses high symmetry and small reactivity. Also, it is the most stable of the alkanes and one of the few thermodynamically stable at room temperature. The temperature at which methane should spontaneously decompose (δG° = 0) is 570°C [2] and its reactions may give valuable information [4].
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