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Synthesis and stereoisomerism of n-oxides of the decahydroquinoline series

 

作者: A.A.Akhrem,   L.I.Ukhova,   N.F.Marcheako,   N.F.Uskova,  

 

期刊: Bulletin of the Academy of Sciences of the USSR, Division of chemical science  (Springer Available online 2004)
卷期: Volume 17, issue 12  

页码: 2628-2632

 

ISSN:0568-5230

 

年代: 2004

 

DOI:10.1007/BF00907788

 

出版商: Springer_US-Boston

 

数据来源: Springer

 

摘要:

1.In the oxidation of 4-ethynyl-, 4-vinyl-, and 4-ethyl-decahydro-1,2-dimethyl-4-quinolinols containing an axial methyl group at C-2 with hydrogen peroxide only one isomer of the N-oxide is formed.2.In the oxidation of 4-ethynyl-, 4-vinyl-, and 4-ethyl-decahydro-1,2-dimethyl-4-quinolinole containing an equatorial methyl group at C-2 with hydrogen peroxide two isomeric N-oxides are formed.3.In the oxidation of the isomeric decahydro-1,2-dimethyl-4-vinyl-4-quinolinols with two molecular proportions of peracetic acid the main products are the corresponding 4-(epoxyethyl)decahydro-1,2-dimethyl-4-quinolinol 1-oxides.

 

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