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Electrical Conductivity and Conduction ESR in Incommensurate Phase of Graphite Intercalation Compounds with Nitric Acid

 

作者: AlbertM. Ziatdinov,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  (Taylor Available online 2000)
卷期: Volume 340, issue 1  

页码: 191-196

 

ISSN:1058-725X

 

年代: 2000

 

DOI:10.1080/10587250008025465

 

出版商: Taylor & Francis Group

 

关键词: graphite intercalation compounds;HNO3;electrical conductivity

 

数据来源: Taylor

 

摘要:

Electrical conductivity and conduction ESR (CESR) of the second stage of graphite intercalation compound (GIC) with nitric acid (C10HNO3) in its incommensurate phase (210 K<T<250 K) are studied. Absence of the temperature dependence of the c-axis conductivity (σc) at preservation of the «« metallic »» temperature dependence of the conductivity along carbon layers (σa) is found. The analysis of the experimental data has shown that in the GIC studied the σc-conductivity realized by means of the non-band mechanism, as which one there can be mechanism of the transport of free charge carriers through the narrow high conductive paths (channels).

 

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