Electrical Conductivity and Conduction ESR in Incommensurate Phase of Graphite Intercalation Compounds with Nitric Acid
作者:
AlbertM. Ziatdinov,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 2000)
卷期:
Volume 340,
issue 1
页码: 191-196
ISSN:1058-725X
年代: 2000
DOI:10.1080/10587250008025465
出版商: Taylor & Francis Group
关键词: graphite intercalation compounds;HNO3;electrical conductivity
数据来源: Taylor
摘要:
Electrical conductivity and conduction ESR (CESR) of the second stage of graphite intercalation compound (GIC) with nitric acid (C10HNO3) in its incommensurate phase (210 K<T<250 K) are studied. Absence of the temperature dependence of the c-axis conductivity (σc) at preservation of the «« metallic »» temperature dependence of the conductivity along carbon layers (σa) is found. The analysis of the experimental data has shown that in the GIC studied the σc-conductivity realized by means of the non-band mechanism, as which one there can be mechanism of the transport of free charge carriers through the narrow high conductive paths (channels).
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