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Density functional models for inhomogeneous hard sphere fluids

 

作者: R.D. Groot,  

 

期刊: Molecular Physics  (Taylor Available online 1987)
卷期: Volume 60, issue 1  

页码: 45-63

 

ISSN:0026-8976

 

年代: 1987

 

DOI:10.1080/00268978700100041

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

A new density functional formalism, that is able to describe an inhomogeneous hard sphere fluid consisting of an arbitrary number of components is presented. The theory for one component is compared with a simplified model for the hard sphere-hard wall system. This investigation shows the existence of a monatomic layer adjacent to the wall appearing as a thermodynamically separate phase, in the solid-fluid coexistence density range.

 

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