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Tunnelling of heavy particles in the low temperature chemistry

 

作者: V.A. Benderskii,   V.I. Goldanskii,  

 

期刊: International Reviews in Physical Chemistry  （Taylor Available online 1992）
卷期: Volume 11, issue 1  

页码: 1-70

 

ISSN:0144-235X

 

年代: 1992

 

DOI:10.1080/01442359209353265

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The quantum dynamics of cryochemical solid-state reactions in the region of the low-temperature limit for the rate constant is considered in the framework of multidimensional nuclear tunnelling when low-frequency displacements of heavy particles lead to the formation of reaction complexes with high barrier transparency.

 

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