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A Quasi-lattice Theory for Compound Forming Molten Alloys

 

作者: A.B. Bhatia,   R.N. Singh,  

 

期刊: Physics and Chemistry of Liquids  (Taylor Available online 1984)
卷期: Volume 13, issue 3  

页码: 177-190

 

ISSN:0031-9104

 

年代: 1984

 

DOI:10.1080/00319108408080778

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The complex formation model of Bhatia and Hargrove (BH) to explain the thermodynamic properties of compound forming A-B alloys is reformulated using a quasi-lattice picture. The formulation is explicitly carried out to an approximation where the pseudo-ternary alloy (of A and B atoms and AμBνcomplexes (μ, ν small integers)), envisaged in BH, is treated in the quasi-chemical approximation. It is advantageous over BH in two major respects: Firstly, it gives useful insight into the two approximations used in BH, since these follow from it by simply going to a lower (zeroth) approximation and setting the coordination numberzof the alloy to bez= 2 andz= ∞. Secondly, unlike the BH approach, it provides also an expression for the short range order parameter α1for nearest neighbours. The effect of varyingzin the formulae is examined and a brief discussion of α1is given.

 

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