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Reaction of 1,1,1-trichloropropene with sulfenyl chlorides and sulfur dichloride

 

作者: A.N.Nesmeyanov,   R.Kh.Freidlina,   R.G.Petrova,   A.B.Terent'ev,  

 

期刊: Bulletin of the Academy of Sciences of the USSR, Division of chemical science  （Springer Available online 2004）
卷期: Volume 8, issue 4  

页码: 629-633

 

ISSN:0568-5230

 

年代: 2004

 

DOI:10.1007/BF00915856

 

出版商: Springer_US-Boston

 

数据来源: Springer

 

摘要:

1.The addition reaction of phenyl- and benzylsulfenyl chlorides and 1,1,1-trichloropropene was examined. It was shown that the addition reaction proceeds contrary to the Markovnikov rule and yields compounds containing the sulfide group in α-position relative to the CClsgroup.2.Sulfur dichloride adds to 1,1,1-trichloropropene with the formation of 1,1,1,3-tetrachloroisopropylsulfenyl chloride

 

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