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The Codimerization and Cotrimerization of Vinylacetylene, Propargyl Alcohol, and Acetylene

 

作者: G.D. Jones,   H.E. Doorenbos,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  (Taylor Available online 1985)
卷期: Volume 22, issue 2  

页码: 161-166

 

ISSN:0022-233X

 

年代: 1985

 

DOI:10.1080/00222338508063303

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Propargyl alcohol was codimerized with acetylene, and 4-penten-2-yn-1-o was obtained. Propargyl alcohol was cotrimerized, but the main product was the homotrimer whether the comonomer was vinylacetylene or 2-methylbutenyne. The cotrimerization of 1,1-dimethylpropargyl alcohol was more easily regulated. With acetylene it gave the m- and p-di-α-hydroxypropylbenzenes.

 

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