Reaction of Xylose and Glycine: Identification of the Major Water Soluble Component
作者:
L. Benzing-purdie,
J.H. Nikiforuk,
期刊:
Journal of Carbohydrate Chemistry
(Taylor Available online 1985)
卷期:
Volume 4,
issue 1
页码: 15-27
ISSN:0732-8303
年代: 1985
DOI:10.1080/07328308508062946
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The reaction of equimolar amounts of D-xylose and glycine in D2O at 68°C resulted in the formation of a twelve carbon compound, as a major product. No intermediate was detected in the formation of this dimer. The eneaminol, formed on reaction of 0.1 molar D-xylose and glycine in H2O, after six weeks was isolated and purified. Based on1H and13C NMR, spin echo Fourier transform experiments, and other spectroscopic techniques including FAB-MS and CI-MS of TMS derivative, the structure: N, N[1-deoxy-D-threo-pent-2-enitol, 1′-deoxy-β-D-threo-pentose (2′,5′)] glycine, was assigned to the product.
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