Reactions of C3H3Ions with Aromatic Hydrocarbons and Alcohols and their Implications for an Ionic Model of Soot Formation
作者:
G. Baykut,
F. W. Brill,
J. R. Eyler,
期刊:
Combustion Science and Technology
(Taylor Available online 1986)
卷期:
Volume 45,
issue 5-6
页码: 233-243
ISSN:0010-2202
年代: 1986
DOI:10.1080/00102208608923854
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Ion/molecule reaction pathways and reaction rate coefficients for both cyclic (cyclo-propenylium) and linear (propargylium) C3H3isomers reacting with aromatic hydrocarbons (benzene, toluene, indene, naphthalene, 1 - and 2-methyl naphthalenes) and alcohols (methanol, ethanol, n-butanol) at low pressures and near room temperature have been determined using ion cyclotron resonance (icr) mass spectrometric techniques. Rate coefficients near the Langevin limit were found for reactions of the propargylium isomer with most of the aromatic hydrocarbons, with charge and hydride transfer reactions predominating. Somewhat lou,er rate coefficients were determined for reactions of the propargylium isomer with the three alcohols, with proton, hydride, and OH-transfer representing the major reaction channels. Implications of these results for an ionic soot formation mechanism are discussed.
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