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The Interaction of Oxygen with Polythiozyl, (SN)x, Electrodes

 

作者: Andrzej Czerwinski,   AnastasiosN. Voulgaropoulus,   JudithF. Johnson,   HarryB. Mark,  

 

期刊: Analytical Letters  （Taylor Available online 1979）
卷期: Volume 12, issue 10  

页码: 1089-1094

 

ISSN:0003-2719

 

年代: 1979

 

DOI:10.1080/00032717908082536

 

出版商: Taylor & Francis Group

 

关键词: Polythiozyl;Electrodes;Oxygen;Adsorption;Surface Functional Groups;background currents

 

数据来源: Taylor

 

摘要:

Studies of the background currents for polythioxyl electrodes in 1NH2SO4supporting electrolyte shows that oxygen strongly chemisorbs on both parallel and perpendicular surfaces. On fresh surfaces the principle product on anodic breakdown is oxygen but on prolonged cycling surface hydroxides of (SN)xare the major surface functional groups at anodic breakdown.

 

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