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Threefold Phosphorus-Nitrogen Reorientation Barrier in Trichlorophosphazocompounds from35Cl NQR Data

 

作者: I.A. Kjunzel,   V.A. Mokeeva,   G.B. Soifer,   E.S. Kozlov,  

 

期刊: Spectroscopy Letters  （Taylor Available online 1975）
卷期: Volume 8, issue 2-3  

页码: 113-117

 

ISSN:0038-7010

 

年代: 1975

 

DOI:10.1080/00387017508067313

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

In the present paper we describe the35Cl NQR investigation of PCl3-reorientations in the molecules of three trichlorophosphazocompounds, Cl3P=NCC1(CC13)2(I), C13P=NP(O)(CC13)2(II), C13P=NCOCF3(III). In order to elucidate the quantitative parameters of the reorientational motion we have used (unlikeI) the temperature dependence of the quadrupole spin-lattice relaxation time T1which is very sensitive to a molecular dynamics2,3.

 

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