Electrical and Optical Responses of an Antiferroelectric Liquid Crystal in SmA, SmCα* and SmC* Phases
作者:
Teiyu Sako,
Yasuyuki Kimura,
Reinosuke Hayakawa,
Nobuhiro Okabe,
Yoshiichi Suzuki,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1995)
卷期:
Volume 263,
issue 1
页码: 81-92
ISSN:1058-725X
年代: 1995
DOI:10.1080/10587259508033572
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The SmA, SmCα* and SmC* phases of an antiferroelectric liquid crystal 4-(1-methylheptyloxycarbonyl) phenyl 4‘-octyloxybiphenyl-4-carboxylate (MHPOBC) have been studied by means of simultaneous measurements of the dielectric constant and the electroclinic coefficient under a dc bias electric field. From the three dimensional representation of the electroclinic coefficient as a function of dc electric field and temperature, it is confirmed that there is no helix with a long pitch in the SmCα* phase and the electric field-temperature phase diagram for these phases is obtained. In the SmA phase near the phase transition temperature, the temperature dependences of the dielectric constant and the electroclinic coefficient are analyzed in terms of the phenomenological theory of Landau type and the parameters appearing in the theory are determined.
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