Comparison of the Aifrey-Price Q-e Scheme and a Simple Molecular Orbital Treatment of Copolymerization
作者:
G.G. Cameron,
D.A. Russell,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1971)
卷期:
Volume 5,
issue 7
页码: 1229-1237
ISSN:0022-233X
年代: 1971
DOI:10.1080/00222337108061102
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A simple Huckel treatment of the transition states for the monomer-radical reactions in free radical copolymerization is developed. The resulting equations for the reactivity ratios are compared with those from the Q-e treatment of Alfrey and Price. It is concluded that the Q-e scheme can be regarded as a version of a molecular orbital approach.
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