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Comparison of the Aifrey-Price Q-e Scheme and a Simple Molecular Orbital Treatment of Copolymerization

 

作者: G.G. Cameron,   D.A. Russell,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  (Taylor Available online 1971)
卷期: Volume 5, issue 7  

页码: 1229-1237

 

ISSN:0022-233X

 

年代: 1971

 

DOI:10.1080/00222337108061102

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

A simple Huckel treatment of the transition states for the monomer-radical reactions in free radical copolymerization is developed. The resulting equations for the reactivity ratios are compared with those from the Q-e treatment of Alfrey and Price. It is concluded that the Q-e scheme can be regarded as a version of a molecular orbital approach.

 

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