Stability of α-Ether type Model Compounds During Chemical Pulping Processes
作者:
H. Tanbda,
J. Nakano,
S. Hosoya,
H-M. Chang,
期刊:
Journal of Wood Chemistry and Technology
(Taylor Available online 1987)
卷期:
Volume 7,
issue 4
页码: 485-497
ISSN:0277-3813
年代: 1987
DOI:10.1080/02773818708085281
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
In order to examine the stability of lignin-carbohydrate complexes (LCC) during alkaline chemical pulping, benzyl ether type LCC model compounds containing different non-phenolic units were synthesized and cooked under chemical pulping conditions. At least 80% of the starting substance was recovered unchanged, from soda, kraft and acid sulfite reactions indicating the benzyl ether linkage in this compound is stable during pulping. Furthermore, by blocking the reactive benzylic hydroxyl group, the cleavage of adjacent β-ether linkages in lignin moiety is retarded.
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