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Ferroelectric properties of poly(vinylidene fluoride‐tetrafluoroethylene)

 

作者: J. C. Hicks,   T. E. Jones,   J. C. Logan,  

 

期刊: Journal of Applied Physics  (AIP Available online 1978)
卷期: Volume 49, issue 12  

页码: 6092-6096

 

ISSN:0021-8979

 

年代: 1978

 

DOI:10.1063/1.324528

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Ferroelectric hysteresis of a copolymer of vinylidene fluoride with tetrafluoroethylene and of uniaxially stretched polyvinylidene fluoride has been observed at 60 Hz at room temperature. The measured remanent polarization of the copolymer was in good agreement with a calculated value using a frozen dipole model and measured piezoelectric coefficients. The dielectric constant for the copolymer has been measured at 1000 Hz as a function of temperature. Also, a set of copolymer films of varying thickness were poled above the melt temperature and their piezoelectric stress coefficientsg31were measured as a function of the poling field. These measurements indicate that the copolymer, when poled above the melt temperature, exhibits bulk polarization. These results suggest that this copolymer is ferroelectric and that poling aligns the dipoles in the &bgr; crystal phase of the material.

 

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