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Diffuse Reflectance Spectra of V(CP)2+on Silica

 

作者: Bo Jonson,   Bernd Rebenstorf,   Ragnar Larsson,  

 

期刊: Spectroscopy Letters  （Taylor Available online 1988）
卷期: Volume 21, issue 3  

页码: 285-290

 

ISSN:0038-7010

 

年代: 1988

 

DOI:10.1080/00387018808075718

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Diffuse reflectance spectra of vanadocene adsorbed on silica were recorded in the spectral region 4000-30 000 cm−1. A d-d band around 13 000 cm−1indicated, that vanadocene formed V(cp)2+on the support when the number of silanol groups was decreased. This cation is suggested to be stabilized by the negative charge of deprotonated silanol groups.

 

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