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Fabrication of Si field emitters by dry etching and mask erosion

 

作者: M. R. Rakhshandehroo,   S. W. Pang,  

 

期刊: Journal of Vacuum Science&Technology B: Microelectronics and Nanometer Structures Processing, Measurement, and Phenomena  (AIP Available online 1996)
卷期: Volume 14, issue 2  

页码: 612-616

 

ISSN:1071-1023

 

年代: 1996

 

DOI:10.1116/1.589145

 

出版商: American Vacuum Society

 

关键词: FIELD EMISSION;CATHODES;SILICON;SILICON OXIDES;MASKING;ETCHING;EROSION;HIGH−FREQUENCY DISCHARGES;PRESSURE DEPENDENCE;MEDIUM VACUUM;HIGH VACUUM;Si;SiO2

 

数据来源: AIP

 

摘要:

A Cl2plasma generated by an electron cyclotron resonance source was used to etch field emitter arrays in Si. Compared to wet etching, emitter arrays with sharper emitter tips and higher packing density can be formed by dry etching. Mask erosion was used to control the etch profile in Si. SiO2masks with different profiles were patterned by wet and dry etching, and the effects of the initial SiO2masks slope and etch conditions on the resultant Si profile were investigated. The lateral etch rate of SiO2decreased from 363 to 150 nm/min as the SiO2slope increased from 17° to 45°. As a result, the slope of the Si etch profile increased from 52° to 78° after dry etching to a depth of 1.8 μm. The ion flux and energy, controlled through coupled microwave and rf power, were used to obtain the desired etch rate and basewidth of the emitters. By increasing the pressure during etching, the lateral etch rate of SiO2was reduced and more vertical Si profiles were developed. As pressure was increased from 0.5 to 10 mTorr, the lateral etch rate of SiO2reduced from 414 to 144 nm/min while the vertical Si etch rate did not change significantly. This caused the slope of the Si etch profile to increase from 42° to 69°. Using the above technique, arrays of sharp emitter tips in Si with 2.2 μm basewidth and 11 μm height were fabricated and packing densities up to 1×107tip/cm2were achieved.

 

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