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Switching from photochemical to photothermal mechanism in laser ablation of benzene sol...
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Switching from photochemical to photothermal mechanism in laser ablation of benzene solutions
作者:
Koji Hatanaka,
Mitsushi Kawao,
Yasuyuki Tsuboi,
Hiroshi Fukumura,
Hiroshi Masuhara,
期刊:
Journal of Applied Physics
(AIP Available online 1997)
卷期:
Volume 82,
issue 11
页码: 5799-5806
ISSN:0021-8979
年代: 1997
DOI:10.1063/1.366447
出版商: AIP
数据来源: AIP
摘要:
Nanosecond KrF excimer laser ablation of benzyl chloride, benzyl alcohol, toluene, ethylbenzene, andn-propylbenzene diluted inn-hexane,n-heptane, dichloromethane, and 1,2-dichloroethane was investigated by time-resolved photographic, photoacoustic, and absorbance measurements. Ablation threshold values,Fth,for high concentration solutions (&agr;=250 cm−1,0.6–1 M) were confirmed to be correlated to photochemical reactivity (&bgr;-bond cleavage) of the solute molecules, whereas no distinct relation betweenFthand boiling point of solvents was observed. Time-resolved absorbance at the laser wavelength was almost constant during the excitation pulse, which means that the main light-absorbing molecules were fixed to the ground-state solutes. It is considered that this type of ablation is initiated by the photochemical fragmentation. On the contrary,Fthobserved in relatively low concentration solutions (&agr;=25 cm−1,0.06–0.1 M) were about twice higher than those for the high concentration solutions, and had no direct correlation with the photochemical reactivity of the solute molecules. The time-resolved absorbance increased during the excitation pulse, and was ascribed to the fact that benzyl radicals produced by the photodissociation of solute molecules absorbed the excitation photons and converted them into heat through “a cyclic multiphotonic absorption process.” Furthermore, morphological aspects observed in nanosecond photography exhibited appreciable differences by varying the solute concentrations. These results clearly mean a concentration-dependent ablation mechanism; the ablation mechanism of the benzene derivative solutions switches from photochemical to photothermal as the solute concentration decreases. ©1997 American Institute of Physics.
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