Kinetic-Spectrophotometric Determination of Traces of Osmium by Its Catalytic Effect on the Oxidation of Pyrogallol Red by Hydrogen Peroxide
作者:
AliA. Ensafi,
B. Rezaei,
期刊:
Analytical Letters
(Taylor Available online 1993)
卷期:
Volume 26,
issue 8
页码: 1771-1785
ISSN:0003-2719
年代: 1993
DOI:10.1080/00032719308021495
出版商: Taylor & Francis Group
关键词: Kinetic catalytic;spectrophotometric;osmium
数据来源: Taylor
摘要:
A Kinetic-spectrophotometric method for the determination of ultra-trace amounts of osmium(VIII) is described. It is based on the catalytic action of osmium(VIII) on the oxidation of pyrogallol red with hydrogen peroxide, yielding a colorless product in neutral medium. The reaction is followed spectrophotometrically by measuring the rate of change in absorbance at 540 nm and 30°C. Os(VIII) in the range 0.005 -100 ng.ml−1can be determined. The proposed method is hardly subject to interferences. The relative standard deviation is 1.5% for 1 ng.ml−1of Os(VIII). The kinetic parameters of the catalyzed and uncatalyzed reactions are reported. The detection limit is 1 pg.ml−1.
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