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Second law: Sears–Kestin statement and Clausius inequality

 

作者: W. Muschik,  

 

期刊: American Journal of Physics  (AIP Available online 1990)
卷期: Volume 58, issue 3  

页码: 241-244

 

ISSN:0002-9505

 

年代: 1990

 

DOI:10.1119/1.16192

 

出版商: American Association of Physics Teachers

 

关键词: THERMODYNAMICS;ADIABATIC PROCESSES;ENTROPY;HEAT FLOW

 

数据来源: AIP

 

摘要:

The Sears–Kestin statement represents a formulation of the second law of thermodynamics, restricted to adiabatic processes, which links equilibrium states and which is cyclic in the work variables (generalized displacements). Two conditions, formulated as axioms, are specified which, together with the Sears–Kestin statement, are necessary and sufficient to derive the Clausius inequality. Because these two additional axioms relate to reversible processes and to compound systems—general items not affecting the second law—the status of the Sears–Kestin statement among all the formulations of the second law is strengthened.

 

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