Second law: Sears–Kestin statement and Clausius inequality
作者:
W. Muschik,
期刊:
American Journal of Physics
(AIP Available online 1990)
卷期:
Volume 58,
issue 3
页码: 241-244
ISSN:0002-9505
年代: 1990
DOI:10.1119/1.16192
出版商: American Association of Physics Teachers
关键词: THERMODYNAMICS;ADIABATIC PROCESSES;ENTROPY;HEAT FLOW
数据来源: AIP
摘要:
The Sears–Kestin statement represents a formulation of the second law of thermodynamics, restricted to adiabatic processes, which links equilibrium states and which is cyclic in the work variables (generalized displacements). Two conditions, formulated as axioms, are specified which, together with the Sears–Kestin statement, are necessary and sufficient to derive the Clausius inequality. Because these two additional axioms relate to reversible processes and to compound systems—general items not affecting the second law—the status of the Sears–Kestin statement among all the formulations of the second law is strengthened.
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