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Rheological and morphological analysis of compatibilized polypropylene/polyamide blends

 

作者: Y. Germain,   B. Ernst,   O. Genelot,   L. Dhamani,  

 

期刊: Journal of Rheology  (AIP Available online 1994)
卷期: Volume 38, issue 3  

页码: 681-697

 

ISSN:0148-6055

 

年代: 1994

 

DOI:10.1122/1.550602

 

出版商: The Society of Rheology

 

关键词: POLYPROPYLENE;POLYAMIDES;VISCOELASTICITY;COPOLYMERS;MORPHOLOGY;VISCOSITY;SHEAR PROPERTIES;COMPATIBILITY;RELAXATION TIME;CAPILLARY FLOW;EMULSIONS

 

数据来源: AIP

 

摘要:

The influence of the compatibilizer, a block copolymer, on the rheological behavior of polypropylene/polyamide blends is discussed here. A dual‐flow behavior has been observed. At low shear rate, the blend viscosity is higher than the viscosity of the matrix, while at a high shear rate the contrary is observed. The morphology of the blends is different in the two domains, with a nodular morphology at low shear rate and a lamellar structure at high shear rate. The low shear rate behavior has been theoretically analyzed using a two‐phase Oldroyd model. The copolymer has been located at the interface and is supposed to dominate the nodular dispersed‐phase behavior. A good agreement has been found for the low‐concentration blend. A model of lamellar flow gives the right response for the high shear rate regime. The copolymer, acting as a lubricant, has an influence on the blend viscosity and the agreement with experimental data is discussed.

 

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