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Polyblends of poly(styrene-b-butadiene-b-styrene) and polystyrene. II. Electron microscopy

 

作者: M. Niinomi,   G. Akovali,   M. Shen,  

 

期刊: Journal of Macromolecular Science, Part B  (Taylor Available online 1977)
卷期: Volume 13, issue 1  

页码: 133-150

 

ISSN:0022-2348

 

年代: 1977

 

DOI:10.1080/00222347708208758

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Electron micrographs of a series of polyblends of poly(styrene-b-butadiene-b-styrene (SBS) and polystyrene (PS) are presented. These poly blends were cast from three different solvents, i.e., tetrahydrofuran—methyl ethyl ketone (THF/ MEK), benzene—heptane, and carbon tetrachloride. PS of four different molecular weights were used. It is shown that when the molecular weight of PS exceeds that in the block copolymer, a third phase in the form of “islands” is formed. Lamellarlike structures are formed in the block domains upon the addition of homopolymer. Stretching perturbs the morphology of the block domains somewhat, and produces craze marks in the PS islands. The craze marks are removed upon annealing. These results are discussed in conjunction with the observed mechanical behavior of the same polyblends reported in Part I of this series.

 

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