Fourier Transform Vibrational Spectra of Magnesium Hydrogenphosphate Trihydrate H. The 2000-370 cm−1Region
作者:
Bojn Šoptrajanov,
Igor Kuzmanovski,
Viktor Stefov1,
Gligor Jovanovsk,
期刊:
Spectroscopy Letters
(Taylor Available online 1999)
卷期:
Volume 32,
issue 5
页码: 703-717
ISSN:0038-7010
年代: 1999
DOI:10.1080/00387019909350019
出版商: Taylor & Francis Group
关键词: Magnesium hydrogenphosphate;newberyite;Fourier transform infrared spectra;Fourier transform Raman spectra.
数据来源: Taylor
摘要:
The Fourier transform infrared and Raman spectra of newberyite, MgHPO4·3H2-O, were studied in the 2000-370 cm-l region. Also investigated were the spectra of a series of partially deuterated analogues. By comparing the spectra recorded at room temperature and those obtained at the boiling temperature of liquid nitrogen and by studying the spectra of the series of partially deuterated newberyite an assignment was proposed for the observed bands. The spectra are fully in line with the crystallographic data and prove that the title compound is a true crystalline hydrate and does not contain H3O+ions in its structure.
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