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Synthesis and Magnetic Property of Adducts of Ruthenium(II,III) Pivalate with 9,10-Anthraquinone

 

作者: Daisuke Yoshioka,   Makoto Handa,   Hiroshi Azuma,   Masahiro Mikuriya,   Ichiro Hiromitsu,   Kuninobu Kasuga,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  （Taylor Available online 2000）
卷期: Volume 342, issue 1  

页码: 133-138

 

ISSN:1058-725X

 

年代: 2000

 

DOI:10.1080/10587250008038256

 

出版商: Taylor & Francis Group

 

关键词: ruthenium(II,III) pivalate;9,10-anthraquinone;crystal structure;magnetic property

 

数据来源: Taylor

 

摘要:

Reaction of tetrakis(pivalato)diruthenium(II,III) cation dimer and 9,10-anthraquinone (aq) gave two kinds of adducts, [{Ru2(piv)4(H2O)}2(aq)]-(BF4)2(1) (pivH = pivalic acid) and [Ru2(piv)4(aq)]n(2), depending on the condition. Very weak antiferromagnetic interaction was observed for1.The X-ray crystal structure of2shows an one-dimensional chain structure.

 

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