Equilibrium and Transport Properties of the Noble Gases and Their Mixtures at Low Density
作者:
J. Kestin,
K. Knierim,
E. A. Mason,
B. Najafi,
S. T. Ro,
M. Waldman,
期刊:
Journal of Physical & Chemical Reference Data
(AIP Available online 1984)
卷期:
Volume 13,
issue 1
页码: 229-303
ISSN:0047-2689
年代: 1984
DOI:10.1063/1.555703
出版商: AIP
数据来源: AIP
摘要:
The report contains a set of easy‐to‐program expressions for the calculation of the thermodynamic and transport properties of the five noble gases (He, Ne, Ar, Kr, Xe) and of the 26 binary and multicomponent mixtures that can be formed with them. The properties in question are second virial coefficientB, viscosity &eegr;, thermal conductivity &lgr;, self‐diffusion and binary diffusion coefficientD, and thermal diffusion factor &agr;T. The calculation of properties is restricted to low densities ( &rgr;≪B/C) but covers the full range of compositions and a temperature interval extending from absolute zero to the onset of ionization. Owing to the careful theoretical basis on which the algorithm has been erected, all properties are thermodynamically consistent with each other. Reference to a selected set of critically evaluated measurements provides a basis for the estimation of uncertainties. The report contains 54 abbreviated tables of numerical data and 86 deviation plots. It is asserted that the results are comparable to the best measurements that could be performed at present.
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