MW and mm wave spectra, octic-order centrifugal-distortion,14N nuclear electric quadrupole coupling, and dipole moment of the gauche tetrafluorohydrazine conformer, N2F4
作者:
U.E. Frank,
W. Herdeg,
PradipN. Ghosh,
W. Hüttner,
期刊:
Molecular Physics
(Taylor Available online 1990)
卷期:
Volume 69,
issue 1
页码: 33-51
ISSN:0026-8976
年代: 1990
DOI:10.1080/00268979000100031
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The ground state rotational spectrum of gauche-N2F4has been investigated between 8 and 200 GHz, including quantum states up toJ= 74 andKa= 39. Quadrupole coupling hyperfine structures were analysed to give χaa= 2·246(12) MHz and χcc= -1·792(5) MHz. The hypothetical (eQ= 0) centre frequencies were fitted using a rigid-rotor hamiltonian including centrifugal-distortion terms up to eighth degree in (J, K). The rotational constants areA= 5576·1995(1) MHz,B= 3189·432 77(8) MHz andC= 2813·169 55(8) MHz. The electric dipole moment along thecaxis was determined from field shifts of magic-doublet components to be μe= 0·256(4) D.
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