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MW and mm wave spectra, octic-order centrifugal-distortion,14N nuclear electric quadrupole coupling, and dipole moment of the gauche tetrafluorohydrazine conformer, N2F4

 

作者: U.E. Frank,   W. Herdeg,   PradipN. Ghosh,   W. Hüttner,  

 

期刊: Molecular Physics  (Taylor Available online 1990)
卷期: Volume 69, issue 1  

页码: 33-51

 

ISSN:0026-8976

 

年代: 1990

 

DOI:10.1080/00268979000100031

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The ground state rotational spectrum of gauche-N2F4has been investigated between 8 and 200 GHz, including quantum states up toJ= 74 andKa= 39. Quadrupole coupling hyperfine structures were analysed to give χaa= 2·246(12) MHz and χcc= -1·792(5) MHz. The hypothetical (eQ= 0) centre frequencies were fitted using a rigid-rotor hamiltonian including centrifugal-distortion terms up to eighth degree in (J, K). The rotational constants areA= 5576·1995(1) MHz,B= 3189·432 77(8) MHz andC= 2813·169 55(8) MHz. The electric dipole moment along thecaxis was determined from field shifts of magic-doublet components to be μe= 0·256(4) D.

 

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