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THE PRODUCTION OF THIXOTROPIC SUSPENSIONS BY CONTROL OF DISPERSANT CONCENTRATION

 

作者: Terry Garino,  

 

期刊: Journal of Dispersion Science and Technology  (Taylor Available online 1997)
卷期: Volume 18, issue 3  

页码: 273-288

 

ISSN:0193-2691

 

年代: 1997

 

DOI:10.1080/01932699708943736

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The effect of dispersant concentration on the rheological behavior of suspensions of Sub-micron aluminum oxide particles in either water or dodecane was studied using a double concentric cylinder rheometer. In the electrosterically stabilized aqueous system, the suspensions underwent a sharp transition from coagulated to dispersed as the concentration of the dispersant, ammonium poly(methacrylate)l, was increased. In the sterically stabilized dodecane system, as the concentration of the dispersant, 12-hydroxy stearic acid ester, was increased, the initially coagulated suspensions became highly thtxotropic at concentrations less than that needed for stability. The difference in behavior between these two systems is caused by the way that the interparticle forces are affected by the concentration of dispersant for the two types of stabilization mechanisms. The technique of inducing thixotropy by control of the dispersant concentration has certain advantages including wide applicability and not requiring special additives.

 

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