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Particle clustering and dielectric enhancement in percolating metal–insulator composites

 

作者: William T. Doyle,  

 

期刊: Journal of Applied Physics  (AIP Available online 1995)
卷期: Volume 78, issue 10  

页码: 6165-6169

 

ISSN:0021-8979

 

年代: 1995

 

DOI:10.1063/1.360560

 

出版商: AIP

 

数据来源: AIP

 

摘要:

An effective cluster model has been developed [Phys. Rev. B42, 9319 (1990)] that treats a disordered suspension of monodisperse metal spheres as a mixture of isolated spheres and close‐packed spherical clusters of spheres using the Clausius–Mossotti or Maxwell equations. The effective cluster model is adapted to such suspensions with a random intermingled cluster topology using Bruggemann’s symmetrical equation. Model susceptibilities for the two cluster topologies are contrasted with one another and compared with experiments. Guillien’s permittivity measurements [Ann. Phys. (Paris) Ser. 1116, 205 (1941)] and Turner’s conductivity measurements [Chem. Eng. Sci.31, 487 (1976)] exemplify nonpercolating island topology suspensions. The permittivity measurements of Grannan, Garland, and Tanner [Phys. Rev. Lett.46, 375 (1981)] exemplify percolating random topology clusters. The models for both cluster topologies are in excellent agreement with experiment over the entire accessible range of volume loading. ©1995 American Institute of Physics.

 

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