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Synthesis of (±)-15-thia-15-deoxy-PGE1methyl ester

 

作者: Herbert L. Holland,   Elaref S. Ratemi,   Luis Contreras,  

 

期刊: Canadian Journal of Chemistry  （NRC Available online 1994）
卷期: Volume 72, issue 1  

页码: 1-5

 

ISSN:0008-4042

 

年代: 1994

 

DOI:10.1139/v94-001

 

出版商: NRC Research Press

 

数据来源: NRC

 

摘要:

The 15-thia-15-deoxy analogue of prostaglandin E1methyl ester has been prepared by the zirconocene chloride mediated conjugate addition of ann-pentyl ethynyl sulfide derived anion to an appropriately substituted cyclopentenone. Similar methodology has also been used to prepare other 3-(3′-thia-1′-octenyl)-cyclopentanones.

 

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