Studies on Template Polymerization
作者:
A.K. Srivastava,
S.K. Nigam,
A.K. Shukla,
S. Saini,
P. Kumar,
N. Tewari,
期刊:
Journal of Macromolecular Science, Part C
(Taylor Available online 1987)
卷期:
Volume 27,
issue 2
页码: 171-180
ISSN:1532-1797
年代: 1987
DOI:10.1080/07366578708081914
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The problem of synthesizing macromolecules of accurately predetermined structure is an intriguing one; not only does such a synthesis provide a challenge to our chemical ingenuity but it also offers the possibility of providing a new range of materials with potentially valuable properties. To achieve a synthesis of this kind, the random features associated with conventional polymerization and copolymerization must be eliminated. Apart from gross structure defects such as chain branching and wrong-way addition, randomness in addition polymerization arises because the nature of the reaction between the propagating chain and the monomer is not uniquely defined. Thus, in homopolym-erization, addition may lead to either iso or syndiotactic placement, while in copolymerization further ambiguity is introduced by the possibility of reaction between a given propagating chain and any monomer species present; similar remarks also apply to conventional condensation copolymerization.
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